Product ID:THERMOFIT S-1006 ADHESIVE PART A
MSDS Date:11/01/1995
FSC:8040
NIIN:00-109-8101
Status Code:A
MSDS Number: CJPBB

Emergency Phone: 800-424-9300

Info Phone: 650-361-4907

Preparer: LINDA MASSEY

Cage: 06090

Telephone: 415-361-4907

Cage: 06090

BISPHENOL A-EPICHLOROHYDRIN EPOXY RESIN (PART A)

CAS: 25068-38-6

RTECS: CE6880000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE CNTCT: THIS MATL IS AN EYE
IRRIT. DIRECT CNTCT W/LIQ/EXPOS TO VAP/MIST MAY CAUSE STINGING,
TEARING, REDNESS, & SWELLING. CNTCT W/MOLTEN MATL MAY CAUSE THERMAL
BURNS. PERS W/PRE-EXISTING EYE DISORDERS MAY BE MORE SUSCEPTIBLE
TO EFTS OF THIS MATL. SKIN: THIS MATL IS A SKIN IRRIT. DIRECT
CNTCT/EXPOS TO VAP/MISTS MAY CAUSE REDNESS & BURNING & SKIN DMG.
RPTD CNTCT MAY CAUSE ALLERGIC SKIN RXN IN SENSITIZED INDIVIDUALS.
PERS W/PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO EFTS
OF THIS MATL. NO HARMFUL EFTS ARE EXPECTED FROM SKIN ABSORPTION OF
MATL. CNTCT W/MOLTEN MATL MAY CAUSE TH ERMAL BURNS. (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:THE INGREDIENTS OF THIS PRODUCT, PRESENT
OR EQUAL TO OR GREATER THAN 0.1% OF THE PRODUCT, ARE NOT LISTED BY
OSHA, NTP, OR IARC AS SUSPECT CARCINOGENS.
Effects of Overexposure:HLTH HAZ: INGEST: INGEST OF THIS MATL IS HIGHLY
UNLIKELY. HOWEVER, IF SWALLOWED, THIS PROD IS EXPECTED TO HAVE A
LOW DEGREE OF TOX BY INGEST. INHAL: BECAUSE OF ITS LOW VOLATILITY,
EXPOS TO VAPS IS UNL IKELY. IN COMMON W/MOST ORG MATLS, THERMAL
DEGRADATION & COMBUSTION BYPRODS MAY BE TOX & SHOULD NOT BE
INHALED. SEE COMMENTS BELOW & THERMAL DEGRADATION & COMBUST ON
BYPRODS SECTION FOR MORE SPECIFIC INFO. CHRONIC: COMPONENT OF PART
A OF THIS PROD (BISPHENOL A-EPICHLOROHYDRIN EXPOXY RESIN) IS
POSITIVE IN IN VITRO MICROBIAL MUTAGENICITY SCREENING (SUPDAT)

First Aid:EYES: HOLD EYELIDS APART & FLUSH AFFECTED EYE(S) IMMED
W/CLEAN H*2O FOR AT LEAST 15 MIN. SEEK IMMED MED ATTN. SKIN: FLUSH
W/PLENTY OF H*2O & WASH AFFECTED AREA(S) W/SOAP & H*2O. REMOVE
CONTAMD CLTHG & WASH BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE
REUSE. CONTAMD LEATHER ARTICLES, INCLUDING SHOES, CANNOT BE
DECONTAMINATED & SHOULD BE DESTROYED TO PVNT REUSE. IF IRRIT
PERSISTS, SEEK MED ATTN. IF C NTCT W/PROD OCCURS, IMMED FLUSH
W/COOL H*2O FOR 15 MIN. CAREFULLY REMOVE CLTHG,IF CLTHG IS STUCK TO
A BURNED AREA DO NOT PULL IT OFF, BUT CUT AROUND IT. COVER BURNED
AREA W/CLEAN MATL & SEEK MED ATTN IMMED. (OTHER INFO)

Flash Point Method:CC
Flash Point:=248.9C, 480.F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL NEARBY CONTAINERS AND
STRUCTURES EXPOSED TO FIRE. DO NOT USE SOLID STREAM APPLIANCE.
Unusual Fire/Explosion Hazard:TOXIC FUMES MAY BE GIVEN OFF IN A FIRE.
SEE SECTIONS ON THERMAL DEGRADATION AND COMBUSTION BYPRODUCTS AND
OTHER PRECAUTIONS.

Spill Release Procedures:WEAR APPROPRIATE PERSONAL PROTECTION WHEN
RESPONDING. CONTAIN SPILL WITH INERT ABSORBENT. TAKE MEASURES TO
STOP SPILLAGE AT THE SOURCE TRANSFER CONTAMINATED ABSORBENT INTO A
CONTAINER AND DISPOSE IN A CCORDANCE TO LOCAL, STATE AND FEDERAL
LAWS. WASH AREA WITH DILUTE (5%) ACETIC ACID, PICKUP WITH INERT
ABSORBENT AND DISPOSE OF PROPERLY.

Handling and Storage Precautions:AVOID CONT W/EYES, SKIN/CLTHING.
CONTAMD LEATHER ARTICLES, INCLUDING SHOES, CANNOT BE DECONTAMD &
SHOULD BE DESTROYED TO PVNT REUSE. AVOID BRTHING VAPORS/MIST.
APPLIC OF ADHESIVE (PARTS A & B) SHOULD BE DONE IN A WELL-VENTD
AREA. STORE INA COOL, DRY AREA.
Other Precautions:CNTNRS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN
CONTAIN HAZ PROD RESIDUES. HANDLE IN ACCORD W/PRECAUTIONS OUTLINED
IN THE HANDLING SECTION ABOVE. PART A & B RELEASE HEAT WHEN
COMBINED. PROTECT PACKETS FROM PHYSICAL DMG TO AVOID LEAKS &
SPILLS. KEEP AWAY FROM OPEN FLAMES & HIGH TEMPS. KEEP CNTNR CLOS
ED.

Respiratory Protection:DEPENDING ON THE AIRBORNE CONCENTRATION OF
MATERIAL, USE A NIOSH APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGES. AT TEMPERATURES ABOVE 300F (149C)
HAZARDOUS THERMAL DEGRADATION PRODUC TS MAY BE RELEASED. THEREFORE,
IF TEMPERATURES EXCEED 300F (149C), AIR-SUPPLIED RESPIRATORS ARE
RECOMMENDED.
Ventilation:IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE, ENSURE
ADEQUATE VENTILATION DURING APPLICATION.
Protective Gloves:RUBBER GLOVES TO PVNT/MIN CONTACT.
Eye Protection:ANSI APPROVED CHEMCIAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGH SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND SHOES. WASH CONTAMINATED CLOTHING BEFORE
REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
Supplemental Safety and Health
EFTS OF OVEREXP: TESTS, & HAS PROD CHROMOSOMAL ABSENCE IONS IN CULTURED
RAT LIVER CELLS. IT HAS, HOWEVER PROVEN TO BE INACTIVE WHEN TESTED
IN VIVO MUTAGENICITY ASSAYS. (NOTE: MUTAGENICITY ASSAYS ARE M EANS
TO IDENTIFY IF CHEM MAY CAUSE CHANGES IN GENETIC MATL (DNA) OF A
CELL). COMMENTS: OVERHEATING MATL (OTHER INFO)

HCC:N1
Boiling Pt:>260.C, 500.F
Vapor Pres:0.03 MM HG @ 77C
Spec Gravity:1.17 (WATER =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:VISCOUS PURPLE LIQUID. NO ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZERS, ACIDS, AND BASES, ESPECIALLY
PRIMARY AND SECONDARY ALIPHATIC AMINES.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT FOR PROLONGED PERIODS
OF TIME.
Hazardous Decomposition Products:THERMAL DEGRADATION & COMBUSTION
BYPRODUCTS: THERMAL DEGRADATION & COMBUSTION BYPROD MAY BE TOX &
SHOULD NOT BE INHALED. THERMAL DEGRADATION IS NOT SIGNIFICANT AT
TEMP ACHIEVED DURING (TOX INFO)
Conditions to Avoid Polymerization:HAZ POLYMERIZATION WILL NOT OCCUR,
POLYMERIZATION MAY OCCUR ABOVE 500F. SOME CURING AGENTS, EG, (TOX
INFO)

Waste Disposal Methods:THIS PRODUCT IS A NON-HAZARDOUS WASTE IN
ACCORDANCE WITH U.S. EPA REGULATIONS. CLASSIFICATION ACCORDING TO
ALL FEDERAL, LOCAL AND STATE HAZARDOUS WASTE REGULATION IS REQUIRED
BEFORE DISPOSAL.

Toxicological Information:POLYM CNDTNS: ALIPHATIC POLYAMINES CAN
PRODUCE EXOTHERMIC REACTIONS WHICH IN LARGE MASSES CAN CAUSE
RUNAWAY POLYMERIZATION AND CHARRING OF REACTANTS. HAZ DECOMP PROD:
PROPER APPLICATION, AS DIRECTED B Y PRODUCT INSTRUCTIONS. AT
TEMPERATURESABOVE 300F OR MOST SIGNIFICANTLY IF THE PRODUCTS ARE
BURNED, THE THERMAL DEGRADATION AND COMBUSTION BYPRODUCTS MAY
INCLUDE, BUT ARE NOT LIMITED TO, CARBON MONOXI DE, AMMONIA,
ALDEHYDES, ACIDS AND OTHER ORGANIC SUBSTANCES AND OXIDES OF
NITROGEN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:DOT PROPER SHIPPING NAME; DOT IDENTIFICATION NO.;
DOT HAZARD CLASSIFICATION: NOT REGULATED.

Federal Regulatory Information:TSCA INVENTORY STATUS: ALL INGREDIENTS
ARE LISTED.
State Regulatory Information:OTHER INFO: IF BRTHING DFCLTIES DEVELOP,
O*2 SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. SEEK IMMEDIATE
MEDICAL ATTENTION. IF VICTIM IS NOT BREATHING, IMMEDIATELY BEGIN
ARTIFICIAL RESPIRATION. KEEP VICTIM WARM AND QUIET, SEEK
IMMEDIATE MEDICAL ATTENTION.